【摘 要】
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Stereodefined β,γ-unsaturated carbonyl compounds are important yet synthetically challenging units in natural products and drugs.Disclosed herein is a mild,ra
【机 构】
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Frontier Institute of Science and Technology, Xi’an Jiaotong University, Xi’an, Shaanxi 710054, Chin
论文部分内容阅读
Stereodefined β,γ-unsaturated carbonyl compounds are important yet synthetically challenging units in natural products and drugs.Disclosed herein is a mild,rapid copper-catalyzed diborylation reaction of cross-conjugated enynones as a step-economic and modularapproach to stereodefined multifunctionalized β,γ-unsaturated ketones by fine control of chemo-,regio-,Z/E and diastereoselectivity.The substrate scope was examined and a possible catalytic cycle was proposed to explain the multifaceted selectivity.
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