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Three new gallium complexes formulated as [Ga(PDA)2][Ga(H2O)(PDA)(phen)]·4H2O(1),[Ga(PDA) 2 ]·(H2IN)·2H2O(2) and [Ga(OH)(PDA)(H2O)] 2(3)(H2PDA=pyridine-2,6-dicarboxylic acid;phen=1,10-phenanthroline;HIN=isonicotinic acid) have been synthesi