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A new 3D luminescent Mn-MOF is synthesized based on a tetraphenylethane-core ligand 1,1,2,2-tetrakis(4-(1H-imidazol-1-yl)phenyl)ethene(tipe),with the formula[Mn(tipe)(bcpf)·(DMF)]n(1,bcpf=4,4?-sulfonyldibenzoic acid).Compound 1 crystallizes in the tr