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A new one-dimensional(1D) coordination polymer [Zn(MMTA)2]n(MMTA=5-mercapto-1-methyl-tetrazole) was synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction. This compound crystallizes in the monoclinic space group C2/c,with cell parameters: a=1.4938(7) nm,b=1.3599(5) nm,c=1.2180(4) nm,β=120.84(3)°,V=2.1243(2) nm3,and Z=8. The deprotonated HMMTA molecule as a μ2-ligand links the zinc center,forming 1D chains,which are futher linked by weak C―H···N hydrogen bonds,forming a three-dimensional supramolecular framework. The compound exhibits intense photoluminescence at room temperature. On the basis of the results of TG/DTA analyses,the structure is thermally stable up to～280℃.
A novel one-dimensional (1D) coordination polymer [Zn (MMTA) 2] n (MMTA = 5-mercapto-1-methyl- tetrazole) was synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction. This compound crystallizes in The monoclinic space group C2 / c with cell parameters: a = 1.4938 (7) nm and b = 1.3599 (5) nm, c = 1.2180 (4) nm, β = 120.84 nm3, and Z = 8. The deprotonated HMMTA molecule as a μ2-ligand links the zinc center, forming 1D chains, which are futher linked by weak C-H ··· N hydrogen bonds, forming a three-dimensional supramolecular framework. The compound indications intense photoluminescence at room temperature. On the basis of the results of TG / DTA analyzes, the structure is thermally stable up to ~ 280 ° C.