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[Fe4O2(O2CCH3)7(2,2’-bipy)2]Cl,Mr=1016.5,monoclinic,C2/c,a=27.628(5),b=11.882(3),c=16.587(3)A,β=119.03(1)°,V=4761.4A3,Z=4,Dc=1.418 g/cm3,λ(MoKa)=0.71069A,μ=13.13 cm-1,F(000)=2088,R=0.062 and Rw=0.077 for 3116 reflections with I≥3σ(I).The title compound contains a [Fe4O2]8+core with bridging CH3COO-and terminal bipy groups giving the structure with a C2 symmetry.The arrangement of the four metal atoms is not planar but has a butterfly-like structure with a dihedral angle of 141.58°.
[Fe4O2 (O2CCH3) 7 (2,2’-bipy) 2] Cl, Mr = 1016.5, monoclinic, C2 / c, a = 27.628 (5), b = 11.882 (3), c = 16.587 (3) β = 119.03 (1) °, V = 4761.4A3, Z = 4, Dc = 1.418 g / cm3, λ (MoKa) = 0.71069A, μ = 13.13 cm -1, F (000) = 2088, R = R w = 0.077 for 3116 reflections with I ≥ 3σ (I). The title compound contains a [Fe4O2] 8 + core with bridging CH3COO-and terminal bipy groups giving the structure with C2 symmetry. The arrangement of the four metal atoms is not planar but has a butterfly-like structure with a dihedral angle of 141.58 °.