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A technique is used to enhance the pressure and temperature sensitivity of a fiber Bragg grating sensor. The grating is packaged by using polymer jacket, which exhibits no significant chirp due to the adoption of the special technique. The measured pressure and temperature sensitivity of the structured grating is 6.28×10-5 / MPa and5.18×10-5/℃. The wavelength shift due to pressure and temperature can be enhanced about 31.5 times for pressure and 7.7 times for temperature.