论文部分内容阅读
本刊84年第1期第148页刊载赵忠提出的Langmuir吸附等温线方程在时,的疑问以及王欲知和高本辉所作的正确解答。这个问题似是由于在上述方程的推导中引用了de Boen关于吸附的定义所引起的(国内出版的有关著作中也多采用这种推导方式)。de Boen为了在他的《The Dynamical Character of Adsorption》一书中形象地阐明吸附理论而提出这个定义。但用这个定义推导吸附方程易于使读者忽视吸附的动态平衡本质(见王欲知答),虽然在数学上也能解答上述方程中的矛盾(见高本辉答),但是物理图象总嫌不
This issue of 84 No. 1, p. 148, published by Zhao Zhong Langmuir adsorption isotherm equation in question, as well as Wang Yoshi and Gao Benhui correct answer. This problem seems to be due to de Boen’s definition of adsorption quoted in the derivation of the above equation. (This type of derivation is often used in domestic publications). de Boen proposed this definition in order to clarify the theory of adsorption in his The Dynamical Character of Adsorption. However, using this definition to derive the adsorption equation tends to neglect the reader’s understanding of the dynamic equilibrium nature of adsorption (see Wang Yuxi), although it mathematically solves the contradiction in the above equation (see Gao Benhui)