手性有机硼化合物是重要的构建碳-碳键和碳-杂键的合成子,被广泛应用于天然产物、生物活性小分子及功能材料的合成中.通过烯烃不对称硼碳化反应来构建手性有机硼化合物是一种简洁高效的方法,目前相关报道非常少.中国科学院成都生物研究所廖建课题组利用铜/钯双金属共催化(串联)策略,首次实现了联硼酸频哪醇酯和烯丙基叔 Chiral organoboron compounds are important synthons for building carbon-carbon bonds and carbon-hetero bonds and are widely used in the synthesis of natural products, small bioactive molecules and functional materials. Asymmetric boron-carbonization of olefins Organo-boron compounds are a simple and efficient method, and there are very few reports on them at present.Liao Jian (Chengdu Institute of Biology, Chinese Academy of Sciences) The first time, the bis (pinacolato) diboron And allyl tert