物理无机化学是一门运用现代物理学的实验与理论方法研究无机化学问题的化学分支学科,包括理论无机化学、结构无机化学、无机化合物反应热力学和动力学以及反应机理等,主要研究无机化合物的反应、制备、结构性能以及有关规律.这一学科的起源可追溯至诺贝尔奖获得者J.H.van’t Hoff和S.Arrhenius(1903年),F.W.Ostwald(1900年)和配位化学创始者A.Werna(1901年)等的早期工作.物理化学的早期发展多以无机化合物为研究对象.无机化学早期也常被喻为狭义的物理化学.20世纪30年代前后,随着基础化学实践深入到原子、分子层次,在量子力学基础上分别建立了酸碱理论、价键理论、分子轨道理论、配位场理论.在近代物理技术的促进下,各种光谱、波谱、能谱和质谱等分析方法对于无机化学的发展起了巨大的促进作用,同时也推动了无机化学与其他化学学科的交叉融合,扩展了无机化学的研究领域,并最终形成了物理无机化学 Inorganic chemistry is a branch of chemistry that uses the experimental and theoretical methods of modern physics to study inorganic chemistry. It includes theoretical inorganic chemistry, structural inorganic chemistry, reaction thermodynamics and kinetics of inorganic compounds, and reaction mechanism. It mainly studies inorganic compounds Reaction, preparation, structural properties and related disciplines.The origins of this discipline can be traced back to Nobel laureates JH van’t Hoff and S. Arrhenius (1903), FWOstwald (1900) and co-founder A .Werna (1901) and other early work .In the early development of physical chemistry mostly inorganic compounds as the research object.Inorganic chemistry is also often described as narrow sense of the early physical and chemical.In the 1930s, with the deepening of basic chemical practice At the atomic and molecular levels, the acid-base theory, valence bond theory, molecular orbital theory and coordination field theory are respectively established on the basis of quantum mechanics. With the help of modern physics, various spectroscopy, spectroscopy, energy spectrum and mass spectrometry Methods for the development of inorganic chemistry played a huge role in promoting, but also promote the cross-integration of inorganic chemistry and other chemical disciplines, expand The field of inorganic chemistry research, and eventually physical Inorganic Chemistry