本文合成了庚烯配位的羰基钌氢簇合物H_3Ru_3(CO)_9(C_7H_(11)),用IR、NMR、MS和元素分析等手段对此簇合物进行了结构表征,推测其为含有金属-氢键的羰基钌簇合物,并且庚烯的双键被打开,X射线衍射测定进一步肯定了上述结论.簇合物为三斜晶系,空间群为PI 晶胞参数:a=0.9726(2)nm,b=0.9868(1)nm,c=1.1104(2)nm,α=103.22(1)°,β=89.89(1)°,γ=91.55(1)°,V =1.0370(3)nm~3,Z=2, μ=21.59cm~(-1),D_σ=2.09g/cm~3,F(000)=628,最终偏差因子R=0.0371 In this paper, He (R) H_3Ru_3 (CO) _9 (C_7H_ (11)) complexes were synthesized and their structures were characterized by IR, NMR, MS and elemental analysis. Hydrogen bond-containing ruthenium carbonyl complexes, and heptene double bond is opened, X-ray diffraction determination to further confirm the above conclusion.The cluster is triclinic, the space group PI cell parameters: a = A = 103.22 (1) °, β = 89.89 (1) °, γ = 91.55 (1) °, V = 1.0370 (2) nm, b = 0.9868 D = σ = 2.09 g / cm ~ 3, F (000) = 628, final deviation factor R = 0.0371