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A kinetic model has been developed for the degradation of organic pollutants concerningwith hydroperoxide ion as the initial step for generation of hydroxyl radical and its subsequent reac-tion mechanisms.Rate equations were derived for depletion of ozone and pollutants in the peroxoneoxidation process using ozone and hydrogen peroxide as combined oxidants.Kinetic data obtainedexperimentally from the hydrogen peroxide-ozone reaction and peroxide oxidation of nitrobenzenewere analyzed by using the proposed rate equations.
A kinetic model has been developed for the degradation of organic pollutants concerning with hydroperoxide ion as the initial step for generation of hydroxyl radical and its subsequent reac- tion mechanisms. Rate equations were derived for depletion of ozone and pollutants in the peroxoneoxidation process using ozone and hydrogen peroxide as combined oxidants. Kinetic data obtainedexperimentally from the hydrogen peroxide-ozone reaction and peroxide oxidation of nitrobenzenewere analyzed by using the proposed rate equation.