论文部分内容阅读
The title complex is of triclinic system space group P1 with its cell parameters: a = 9. 386(1), b = 9. 412(2), c=11. 549(2)(?), α=97. 91(2), β = 81.70(1), γ= 102. 63(1)°, V= 979.2(?)3, Z = l, Mr = 966. 01, Dx =1. 638 gcm-3, μ(MoKα) = 16. 896cm-1, F (000) = 478, final R = 0. 033 and Rw = 0. 046 for 3424 reflections with I≥3σ(I). The two O atoms of the ligand are bonded to two Sn atoms to form a bridged binuclear species which lies on the crystallographic centre of symmetry situated at the centre of the ethylene C -C bond. The unique Sn atom exhibits a trigonalbipyramidal geometry.
The title complex is of triclinic system space group P1 with its cell parameters: a = 9. 386 (1), b = 9. 412 (2), c = 11. 549 (2) Β = 81.70 (1), γ = 102. 63 (1) °, V = 979.2 (?) 3, Z = l, Mr = 966.01, Dx = 1.638 gcm-3, μ (R = 0. 033 and Rw = 0. 046 for 3424 reflections with I ≥ 3σ (I). The two O atoms of the ligand are bonded to two (MoKα) = 16. 896 cm -1, F Sn atoms to form a bridged binuclear species which lies on the crystallographic center of symmetry situated at the center of the ethylene C -C bond. The unique Sn atom exhibits a trigonalbipyramidal geometry.