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在二异丙苯基氯/BCl3/CH2Cl2/异丁烯聚合体系中.用BBr3代替BCl3进行聚合。通过测定聚合物的卤素官能团,以检验INIFER修正机理的正确性。结果表明,聚合物中溴官能度/氯官能度约为3:1。证明对J.P.Kennedy教授的INIFER机理的修正是正确的。
In dicumyl chloride / BCl3 / CH2Cl2 / isobutylene polymerization system. BBr3 was used instead of BCl3 for polymerization. By measuring the halogen function of the polymer, in order to test the correctness of INIFER correction mechanism. The results show that the bromine functionality / chlorine functionality in the polymer is about 3: 1. Prove to J. P. Professor Kennedy’s amendment to the INIFER mechanism is correct.