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基于铁和锰的双核配合物在生物氧化还原过程中的重要作用及在化学的氧化还原过程中可能做为催化剂的应用前景,本文合成了两个新的以氯醌酸二价阴离子为桥联配体的Fe(Ⅲ)双核和Mn(Ⅱ)双核配合物:[Fe_2(phen)_4(μ-CA)](ClO_4)_4·2H_2O(1)和[Mn_2(phen)_4(μ-CA)](ClO_4)_2·3H_2O(2)(phen=1,10菲咯啉;CA=氯醌酸二价阴离子)。经元素分析、IR、电子光谱及磁性等测定,对两配合物进行了表征。
Based on the important role of binuclear iron and manganese binuclear complexes in the biological redox process and potential applications as catalysts in the redox process of chemical reactions, two novel chloroquinic acid dianions The complexes of Fe (Ⅲ) binuclear with Mn (Ⅱ): [Fe_2 (phen) _4 (μ-CA)] (ClO_4) _4 · 2H_2O and Mn_2 (phen) _4 ] (ClO_4) _2 · 3H_2O (2) (phen = 1,10 phenanthroline; CA = chloroquinic acid dianion). The two complexes were characterized by elemental analysis, IR, electronic spectra and magnetic measurements.