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The complex monoaqua[(9-hydroxy-fluorene-9-carboxylato)(N,N-Dimethylisopro- panolamine)]copper(II) semihydrate, Cu(C14H8O3)(C5H13NO)(H2O)]0.5H2O (Mr = 417.93), crystallizes in triclinic system, space group P with a = 9.846(2), b =12.419(3), c =16.781(3)? =75.55(3), b = 75.00(3), g = 84.58(3), V =1918.5(7)?, Z = 4, F(000) =872, Dc=1.45g/cm3 and m= 1.17mm-1. The final R and wR are 0.0481 and 0.1427 for 7099 observed reflections, respectively. The coordination polyhedron around the copper atom is a distorted square pyramid, the basal plane consisting of one carboxyl oxygen atom and one -hydroxylated oxygen atom from a 9-hydroxy-fluorene-9-carboxylato ligand, one nitrogen atom and one oxygen atom from the N,N-dimethylisopropanolamine ligand; while the axial coordination site is occupied by a water oxygen atom with a Cu-O bond length of 2.428(3)?
The complex monoaqua [(9-hydroxy-fluorene-9-carboxylato) (N, N-Dimethylisopro- panolamine)] copper (II) semihydrate, Cu (C14H8O3) (C5H13NO) (H2O)] 0.5H2O (Mr = 417.93) crystallizes in triclinic system, space group P with a = 9.846 (2), b = 12.419 (3), c = 16.781 (3)? = 75.55 (3), b = 75.00 (3), g = 84.58 V = 1918.5 (7) ?, Z = 4, F (000) = 872, Dc = 1.45g / cm3 and m = 1.17mm-1. The final R and wR are 0.0481 and 0.1427 for 7099 observed reflections, respectively. coordination polyhedron around the copper atom is a distorted square pyramid, the basal plane consisting of one carboxyl oxygen atom and one -hydroxylated oxygen atom from a 9-hydroxy-fluorene-9-carboxylato ligand, one nitrogen atom and one oxygen atom from the N , N-dimethylisopropanolamine ligand; while the axial coordination site is occupied by a water oxygen atom with a Cu-O bond length of 2.428 (3)?