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The reaction between [Mn(bpy)2(MeOH)2](SbF6)2 (bpy = 2,2′-bipyridine) and(Et4N)[Ni(pymt)3] (pymt = pyrimidine-2-thiolate) gave the complex [Ni(bpy)2(pymt)](SbF6) which was determined by X-ray single-crystal diffraction. The structure is of monoclinic with