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The Eu~(3+):BaMoO_4 nanostructures were synthesized by a simple hydrothermal method, and characterized by XRD, transmission electron microscopy, high-resolution transmission electron microscopy, excitation and emission spectra. Eu~(3+):BaMoO_4 nanostructures show a lotus leaf-shaped morphology, and exhibit a strong red emission at 612 nm, which may afford an opportunity for the development of other nanostructure materials.