Ti-Hf binary alloys contained 10%,20%,30% and 40%(mass fraction)Hf were manufactured in the vacuum furnace system.And then,specimens were homogenized for 24 h at 1 000 ℃ in argon atmosphere.The formation of oxide nanotubes was conducted by anodic oxidation on the Ti-Hf alloy in 1 mol/L H3PO4 electrolytes containing small amounts of NaF at room temperature.The hydroxyapatite(HA) coating made of tooth ash prepared by electron-beam physical vapor deposition(EB-PVD) method.The corrosion behaviors of the specimens were examined through potentiodynamic test in 0.9% NaCl solution by potentiostat.The microstructures of the alloys were examined by field emission scanning electron microscopy(FE-SEM) and x-ray diffractometer(XRD).It was observed that the lamellar structure translated to needle-like structure with Hf contents.Nanotube formed and HA coated Ti-xHf alloys had a good corrosion resistance. Ti-Hf binary alloys contained 10%, 20%, 30% and 40% (mass fraction) Hf were manufactured in the vacuum furnace system. And then then the specimens were homogenized for 24 h at 1 000 ° C in argon atmosphere. The formation of oxide nanotubes was conducted by anodic oxidation on the Ti-Hf alloy in 1 mol / L H3PO4 electrolytes containing small amounts of NaF at room temperature. The hydroxyapatite (HA) coating made of tooth ash prepared by electron-beam physical vapor deposition (EB- PVD) method. The corrosion behaviors of the specimens were examined by potentiodynamic test in 0.9% NaCl solution by potentiostat. The microstructures of the alloys were examined by field emission scanning electron microscopy (FE-SEM) and x-ray diffractometer (XRD). It was observed that the lamellar structure translated to needle-like structure with Hf contents. Nootube formed and HA coated Ti-xHf alloys had a good corrosion resistance.