论文部分内容阅读
The title complex [Cu(ampym)(bapa)Cl](ClO4) (C10H22Cl2CuN6O4) was synthesized and characterized by elemental analysis, IR and X-ray single-crystal diffraction. The crystal crystalli- zes in the orthorhombic system, space group Pna21 with a = 11.9904(12), b = 15.9796(16), c = 8.9143(9) ’, V = 1708.0(3) ·3, Mr = 424.78, Z = 4, F(000) = 876, Dc = 1.652 g/cm3, T = 293 K, μ = 1.619 mm–1 and λ = 0.71073 ’. The structure was refined to R = 0.0240 and wR = 0.0564 for 2905 observed reflections with I > 2σ(I). Flack = 0.039(12).
The title complex [Cu (ampy) (bapa) Cl] (ClO4) (C10H22Cl2CuN6O4) was synthesized and characterized by elemental analysis, IR and X-ray single-crystal diffraction. The crystal crystallites of the orthorhombic system, space group Pna21 with = 11.9904 (12), b = 15.9796 (16), c = 8.9143 (9) ’, V = 1708.0 (3) · 3, Mr = 424.78, Z = 4, F (000) = 876, Dc = 1.652 T = 293 K, μ = 1.619 mm-1 and λ = 0.71073 ’. The structure was refined to R = 0.0240 and wR = 0.0564 for 2905 at reflections with I> 2σ (I). Flack = 0.039 ).