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PbO-ZnO-Na2O ceramic coating was fabricated on the AZ91D Mg-alloy substrate surface by using of evaporated patt casting (EPC) process. The ceramic coating was characterized through scanning electron microscopy (SEM) observation, energy dispersive X-ray spectrometer (EDS) and so on. The research was emphasized on the formation process of ceramic coating and the interface bonding conditions between ceramic coating and the substrate. Results show that the glass powder (PbO-ZnO-Na2O) melts when contacts with the high temperature liquid metal, and solidifies on the surface of the substrate with the decrease of temperature. Therefore,the ceramic coating was successfully prepared with the formation of the bonding interface with the substrate.Beside the influence of coating layer thickness, the vacuum level was also investigated. Further analysis indicates that oxide inclusions and decomposition products of foam patt had a significant effect on the bonding interface.To obtain a good bonding interface between the ceramic coating and the substrate, the metal liquid oxidation and inclusions must be decreased and the decomposition products of foam patt should be exhausted from the EPC coating completely.