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测定了标题３个化合物乙腈溶液的电子光谱，应用简化为Ｏｈ对称性的配位场理论以解释其ｄ－ｄ跃迁光谱，计算出化合物中有关金属离子的配位场参数，发现四核物中不同结构环境的相同金属离子能敏感地在谱学性质上反映出其差异。
The electronic spectra of the three compounds were determined. The ligand field simplified to Oh symmetry was used to explain the d-d transition spectra, and the coordination fields of the metal ions in the compounds were calculated. It was found that in the tetranuclear species The same metal ions in different structural environments can sensitively reflect their differences in spectral properties.