【摘 要】
：
The adsorption heat and reaction rate constant of potassium dichromate on the surface of galena were studied. The results indicate that potassium dichromate ten
【机 构】
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College of Chemistry and Chemical Engineering, Guangxi University,College of Resources and Metallurg
【出 处】
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International Journal of Minerals Metallurgy and Materials
论文部分内容阅读
The adsorption heat and reaction rate constant of potassium dichromate on the surface of galena were studied. The results indicate that potassium dichromate tends to adsorption on the galena surface. The reaction order is only 0.08385, suggesting that the concentration of potassium dichromate has little influence on its adsorption on the galena surface. In addition, the simulation of 24CrO-adsorption on the PbS(100) surface in the absence and presence of O2 was carried out by density functional theory(DFT). The calculated results show that 24CrO-species adsorb energetically at the Pb–S bond site, and the presence of O2 can enhance this adsorption.
The results indicate that potassium dichromate tends to adsorption on the galena surface. The reaction order is only 0.08385, suggesting that the concentration of potassium dichromate has little influence on In addition, the simulation of 24CrO-adsorption on the PbS (100) surface in the absence and presence of O2 was carried out by density functional theory (DFT). The calculated results show that 24CrO-species adsorb energetically at the Pb-S bond site, and the presence of O2 can enhance this adsorption.
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