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把载有金属盐(M)乙二醇(S)溶液的6201担体作为色谱柱,再将各种不饱和烃(U)分别注入色谱柱中,此时在液相中存在如下的配合平衡:其平衡常数可由下式计算:[U]_L+[M]_L [U·M]_L H=K_L+K_IK_L[M]_LH为不饱和烃在固定相(液相)与流动相(气相)间的分配系数.K_L为不饱和烃不发生配合作用时在固定相与流动相间的分配系数,K_I为平衡常数,H对金属盐浓度M进
The 6201 carrier containing the metal salt (M) glycol (S) solution was used as a chromatographic column, and various unsaturated hydrocarbons (U) were separately injected into the chromatographic column. At this time, the following complexing equilibrium existed in the liquid phase: The equilibrium constant can be calculated by the following formula: [U] _L + [M] _L [U · M] _L H = K_L + K_IK_L [M] _LH is the ratio of unsaturated hydrocarbons between the stationary phase (liquid phase) and the mobile phase Partition coefficient K_L is the partition coefficient between the stationary phase and the mobile phase when the unsaturated hydrocarbon does not coordinate, K_I is the equilibrium constant, H is the concentration of the metal salt M