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过渡金属原子簇化学是当今化学学科中非常活跃的研究领域之一.由于它对合成化学和理论化学具有重要意义,以及它在催化和超导等方面的应用前景,而倍受各国化学家的重视.金属交换反应是一种重要的合成异核金属羰基簇合物的途径[1].我们也曾经研究了以ＳＦｅＣｏ2(ＣＯ)9为前体簇
Transition metal cluster chemistry is one of the most active fields of chemistry in today’s chemistry. Because of its importance to synthetic chemistry and theoretical chemistry, and its applications in catalysis and superconductivity, Attention .Metal exchange reaction is an important way to synthesize heteronuclear metal carbonyl clusters [1] .We have also studied the SFeCo2 (CO) 9 as a precursor cluster