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The title complex {[AgL]ClO4}n(L=2,5-bis(3-pyridinylmethylthio)-1,3,4-thiadiazole) was synthesized by the reaction of Ag(I) salt and a novel flexible ligand L.Its structure was determined by X-ray crystallography with the following data:monoclinic,space group P21/n,a=16.5068(13),b=7.6548(4),c=16.5521(13),β=115.119(3)o,V=1893.7(2)3,Z=4,Dc=1.893 g/cm3,μ=1.565 mm-1,F(000)=1072,C14H12AgClN4O4S3,Mr=539.78,T=293(2) K,S=1.067,the final R=0.0342 and wR=0.0870.The silver ion in the complex is in a trigonal coordination geometry to link three different L.Meanwhile,each L connects three different silver ions by its N coordination sites to form a two-dimensional layer structure.
The title complex {[AgL] ClO4} n (L = 2,5-bis (3-pyridinylmethylthio) -1,3,4-thiadiazole was synthesized by the reaction of Ag (I) salt and a novel flexible ligand L. Its structure was determined by X-ray crystallography with the following data: monoclinic, space group P21 / n, a = 16.5068 (13), b = 7.6548 (4), c = 16.5521 (13) (1), V = 1893.7 (2) 3, Z = 4, Dc = 1.893 g / cm3, μ = 1.565 mm-1, F (000) = 1072, C14H12AgClN4O4S3, Mr = 539.78, T = 293 S = 1.067, the final R = 0.0342 and wR = 0.0870.The silver ion in the complex is in a trigonal coordination geometry to link three different L.Meanwhile, each L connects three different silver ions by its N coordination sites to form a two -dimensional layer structure.