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Reactions of ZnCl2 with 4'-(2,4-Disulfophenyl)-2,2':6'2''-Terpyridine(H2DSPT)result to two new compounds with formula,{[Zn(DSPT)(H2O)2]·2H2O}n(1)and {[Zn(DSPT)(H2O)2]·H2O}n(2),respectively.