【摘 要】
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Thanks to superior redox potential of platinum(Ⅱ) complex 1 to that of Ru(bpy)32+ in the excited state,[1] an efficient and selective visible-light-induced CDC reaction[2] has been developed by using
【机 构】
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Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Phys
论文部分内容阅读
Thanks to superior redox potential of platinum(Ⅱ) complex 1 to that of Ru(bpy)32+ in the excited state,[1] an efficient and selective visible-light-induced CDC reaction[2] has been developed by using 0.25％ catalytic amount of 1.With the aid of 2 equiv of FeSO4, the corresponding amide could not be detected under visible light irradiation (λ =450 nm), but the desired cross-coupling product was obtained at ambient air condition exclusively.
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