Novel multilayer Mg-Al intermetallic coating for corrosion protection of magnesium alloy

来源 :2012 Postdoctoral Symposium of China on Materials Science & | 被引量 : 0次 | 上传用户:laumood
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  A novel multilayer Mg-Al intermetallic coating on magnesium alloy was successfully obtained by AlCl3-NaCl molten salt bath treatment.Molten salt bath treatment at 400℃, which is lower than the treatment temperature of the solid diffusion Al powder, results in the formation of thick Al12Mgl7, Al0.58Mg0.42 and Al3Mg2 multilayer Mg-Al intermetallic coating.In contrast to the conventional powder pack solid diffusion process, active Al atoms can be formed at a lower temperature in molten salts, which contributes to the lower temperature formation of continuous intermetallic layers.The corrosion resistance of AZ91D alloy without and with coating by multilayer of Mg-Al intermetallic compound was evaluated by electrochemical impedance spectroscopy measurements in 3.5 wt% NaCl solution.Therefore, the polarization resistance of the multilayer coating on magnesium alloy by molten salt bath treatment was greater than the uncoated one, which is attributed to the homogenously distributed intermetallic phases.
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