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  5. The effects of substituents,axial ligands,and rates of electrons transfer for cobalt corrole complex

The effects of substituents,axial ligands,and rates of electrons transfer for cobalt corrole complex

来源 :2017年中西部地区无机化学化工学术研讨会 | 被引量 : 0次 | 上传用户：rabbitwangli
【摘 要】
：
Three cobalt complexes of 5,10,15-tris(pentafluorophenyl)corrole(1)and 5,15-bis-(pentafluorophen yl)-10-(4)-(1-pyrenyl)phenylcorrole(2)with pyridine(py)and triphenyl phosphine(tpp)as axial ligands(1-p
【作 者】
：
Xia-Liang Li Hai-Tao Lei Rui Cao 
【机 构】
：
School of Chemistry and Chemical Engineering,Shaanxi Normal University,Xi'an 710119
【出 处】
：
2017年中西部地区无机化学化工学术研讨会
【发表日期】
：
2017年10期
【关键词】
：
cobalt corrole homogeneous catalysis heterogeneous catalysis noncovalent graftin 
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　　Three cobalt complexes of 5,10,15-tris(pentafluorophenyl)corrole(1)and 5,15-bis-(pentafluorophen yl)-10-(4)-(1-pyrenyl)phenylcorrole(2)with pyridine(py)and triphenyl phosphine(tpp)as axial ligands(1-py,2-py,and 2-tpp,respectively)had been investigated to catalyze hydrogen production in acetonitrile(benzoic acid as the source of protons)and aqueous solutions(0.1 M phosphate buffer)in detail.
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