Two Series of Ln(Ⅲ)-Ag(Ⅰ)Heterometallic-Organic Frameworks Constructed from Isonicotinate and 2,2

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  Two new series of two-dimensional(2-D)lanthanide-silver heterometallic-organic frameworks with the formula [Ln2Ag(IN)2(BPDC)2(H2O)4]·(NO3)·2H2O(1-Ln)(Ln = Nd 1,Eu 2,Tb 3,Dy 4)and [Ln2Ag(IN)2(BPDC)2(H2O)2]·(NO3)·2H2O(2-Ln)(Ln =Ho 5,Yb 6,HIN= isonicotinic acid,H2BPDC=2,2'-biphenyldicarboxylic acid)have been hydrothermally synthesized and characterized by single crystal X-ray diffraction,elemental analysis,IR,thermogravimetric analyses(TGA)and powder X-ray diffraction(PXRD).
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