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The technical feasibility of calcium oxide as a sorbent for CO2 and a Fe-Cr Water Gas Shift(WGS)catalyst as the catalyst for Water Gas Shift reaction in syngas for steam gasification of biomass was investigated.The gasification experiment research of pine sawdust with steam as agent was carried out.The effects of temperature,steam to biomass mass ratio,CaO to biomass molar ratio and Fe-Cr WGScatalyst on gas composition were studied.Within the temperature range of 250~550℃,the H2 concentrationincreasesfrom 1.18%to 17.13%with an increase of 15.95%.