改进QuEChERS方法结合LC-MSMS测定蔬菜中的全氟有机物

来源 :第四届环渤海色谱质谱学术报告会 | 被引量 : 0次 | 上传用户:xiao531313486
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
全氟有机物(PFCs),尤其是全氟辛烷磺酸(PFOS)和全氟辛酸(PFOA)是一类新型持久性存在的有机污染物,具有强稳定性的C-F键结构,使其疏水疏油,并在自然环境中难光解、难代谢、难生物降解,且能够伴随食物链的传递在生物机体内富集,生物蓄积性强.因全氟有机物具有很高的化学、生物和热稳定性,被广泛应用在工业、商业及消费品中.例如作为地毯、皮革、炊具、运动衣、纸、食品容器及纺织品的表面保护材料;消防泡沫、地板蜡、洗发露、油漆及墨水中的高性能化学品;工业中的表面活性剂、乳化剂、湿润剂、添加剂以及不粘锅涂层等.本研究以蔬菜样品为研究对象,基于改进的QuEChERS方法结合磁性纳米粒子以及具有高灵敏度和选择性的高效液相色谱串联质谱(HPLC-MS/MS)对全氟化合物进行检测分析。
其他文献
Polypyridyl and related ligands have been widely used in the construction of water oxidation catalysts.Supposedly these ligands are oxidation resistant and can
会议
Simultaneous cancer imaging, therapy and real-time quantitative therapeutic monitoring can prevent over-or under-treatment.1 Taking advantage of molecular desig
会议
The new triple-decker sandwich-type lanthanide complexes with phthalocyanine and redox-active Schiff base ligand including tetrathiafulvalene (TTF) units have b
会议
The oxidation of various alkanes catalyzed by [MnⅤ(N)(CN)4]2-using various terminal oxidants at room temperature has been investigated.Excellent yields of alco
会议
Solar-driven water splitting to generate dihydrogen (H2) and dioxygen (O2) has long been recognized as a sustainable and renewable energy source.Recently, our g
会议
毛樱桃叶为蔷薇科李属植物毛樱桃Cerasus tomentosa(Thunb.)Wall.的叶片,收录于《中华本草》,味辛、苦,性温、无毒,具有温胃、健脾、止血、解毒的功效,并能降压,用于治疗胃寒
Lanthanide complexes have attracted considerable attention for their potential application in optical and magnetic field.1 By employing two types of linear liga
会议
The oxidation of ascorbic acid (H2A) by [RuⅥ(N)(salchda)(MeOH)]+ (salchda =N,N-bis(salicylidene)-o-cyclohexyldiamine dianion) has been studied in aqueous acidi
会议
近几年,网络销售日益盛行,电商代购广受欢迎.在网络平台购买化妆品已成为一种主流消费模式.然而,代购化妆品缺乏安全性是一大不可忽视的弊端.特别是好评不断、快速兴起的高效
法医毒物学检验工作中,由于毒物种类繁多、案件复杂多样,检验目标的不确定性、检验范围的广阔性,常以多目标毒物筛查和常见未知毒物筛查为主要内容.目前筛查方法有免疫法、气