Hydrothermal in situ ligand reaction affording a novel uranylcarboxyphosphonate:synthesis,structure

来源 :第九届全国无机化学学术会议 | 被引量 : 0次 | 上传用户:zhoushucheng0533
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  A novel uranyl carboxyphosphonate(H2dipy)[(UO2)3(H2O)2(H2DPTP)2]·2H2O [H6DPTP = 2,5-diphosphonoterephthalic acid,dipy = 4,4-bipyridine] has been synthesized under hydrothermal condition.
其他文献
Metal-organic coordination polymers,which constructed from metal ions and multifunctional organic ligands,as an important class of solid-state materials have potential applications in gas-storage,phot
The crystal engineering of metal-organic frameworks(MOFs)has grown into a subject that attracts intense attention because controlling the molecular organization in the solid state can lead to material
In the past decades,copper complexes of pyrazolate ligands have been extensively studied due to their structural chemistry and their potential applications in advanced materials and catalytic processe
The reactions of copper(Ⅰ)salts CuX [X = Cl,OTf(OTf = CF3SO3)and ClO4] and bis(diphenylphosphino)methane(dppm)with 4,4-bipyridine(bipy),2,2-bipyridine(bpy),isoquinoline and 1,10-phenanthroline(Phen)le
Metal-organic coordination polymers(MOCP)has promising aspects in areas of gas storage,drug delivery and catalysis owing to their fine-tunable structures[1] and pore size tunability[2].
A novel metal-organic coordination compound,[Zn(μ2-OH)(ATZ)]n(ATZ = 5-amino-1H-tetrazole),has been synthesized through hydrothermal reaction using 5-amino-1H-tetrazole and Zn(NO3)2 as a starting mater
Compound 1 is a linear molecule and the pentafluorobenzene rings are approximately coplanar with the aromatic rings [dihedral angle 5.2°],which promote to form a 2D net.
多孔晶态材料不仅具有新颖的结构,在化学、材料、生物、医药等方面还展现出潜在的应用前景,近年来受到研究者的广泛关注.美国化学会和英国皇家化学会的权威评论杂志Chem.Rev.和Chem.Soc.Rev.特别安排了几期从多个方面对这一热门的研究领域进行了综述[1-3],其中,气体吸附与存储、非均相催化、荧光探针、生(药)物载体等是多孔晶态材料探索的主要方向.
Porous coordination polymers(PCPs)or metal organic frameworks(MOFs),1 have demonstrated significant promise for gas adsorption and separation because of their chemical tailorability,which results in h
金属硫(硒)代锡酸盐由于其丰富的结构和优异的性能,对其研究一直受到广泛关注[1,2]。近年来,以有机胺阳离子作为结构导向剂组装金属硫属化物微孔材料已成为一个重要的研究方向。