Effects of the distance between the inductance coil and substrates on the microstructure and optical

来源 :第四届国际表面与界面科学与工程学术会议(The Fourth International Conference on S | 被引量 : 0次 | 上传用户:w370724
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  Inductively coupled plasma (ICP) system with the adjustable distance (d) between the inductance coil and substrates was designed to effectively utilize the spatial confinement of ICP discharge,and then control the gas-phase transport process.The effects of the distance on the microstructures and optical properties of silicon films were systematically investigated in our work.The investigation was conducted in the ICP-chemicai vapor deposition process with a mixture of SiH4/H2 as the source gas at a low temperature of 240 ℃.Characterization of the films with X-ray diffraction and Rarnan spectroscopy revealed that the crystallinity and crystalline size firstly increased and then decreased with the distance increase.The maximum was reached at the distance of 5 cm.By SEM measurements,the film morphologies were shown to be consistent with the XRD and Raman analysis results.The Fourier transform infrared (FTIR) spectroscopic analysis showed the hydrogen was predominantly incorporated in the silicon films in the mono-hydrogen (Si-H) bonding configuration.With increasing the distance,the hydrogen content in the silicon films exhibited similar behavior with crystailinity of silicon films.Based on the results,a gas-phase transport progress was suggested for the deposition of silicon films in ICP-CVD system.Furthermore,the Taucs optical band gap achieved the maximum of 1.68 eV with the distance of 5 cm.Besides the effect of hydrogen content,the quantum size effect might also responsible for higher band gap in crystalline silicon films.
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