论文部分内容阅读
在已报道的{As2Mo6O26}化合物中,As源多为有机砷或As2O3[1],由于As2O3是剧毒物质,因此砷钼化合物的报道较少,我们以低毒的NaAsO2为砷源,利用水热法,合成了一种结构新颖的基于{As2Mo6O26}建筑块的有机-无机杂化物。
{Cu(H2O)2(bib)}修饰的{As2Mo6}有机-无机杂化物的合成及晶体结构
【摘 要】
：
在已报道的{As2Mo6O26}化合物中,As源多为有机砷或As2O3[1],由于As2O3是剧毒物质,因此砷钼化合物的报道较少,我们以低毒的NaAsO2为砷源,利用水热法,合成了一种结构新颖的基于{As2Mo6O26}建筑块的有机-无机杂化物。
【机 构】
：
功能材料的设计合成与绿色催化黑龙江省高校重点实验室 哈尔滨师范大学 哈尔滨 150025
【出 处】
：
第九届全国无机化学学术会议
【发表日期】
：
2015年7期
其他文献
金属卟啉框架材料(MPFs)是一类特殊的金属-有机框架材料(MOFs)，它由卟啉或金属卟啉单元构筑而成，不但具有常规MOFs规则多孔的框架结构，而且具有卟啉的优秀的功能性，可以实现在吸附、发光和催化等诸多领域的应用[1-6]，是当前配位化学以及材料科学研究的热点。
The engineering of MOFs tends to be the most rapidly investigated area not only due to their intriguing architectures but also because that a great number of MOFs have been proven to be potential func
Tuning the Subunits in Manganese-Cluster-Based Coordination Polymers by Varying the Reaction Conditi
Metal-organic frameworks(MOFs)that are based on the complexation of metal clusters with organic ligands have attracted wide attention not only because of their diverse structures but also their potent
Two new chiral metal-organic coordination polymers,[Cd2(dpb)(H2hfipbb)2]n(1)and [Zn(dpb)(H2hfipbb)]n(2),were obtained under hydrothermal conditions of 1,3-di(pyridineyl)benzene(dpb)and 4,4-(hexafluoro
随着微电子学的迅速发展,分子水平的电子器件材料受到人们的广泛关注,具有双稳态性质的自旋交叉类金属配合物是一类非常有希望应用于单分子器件研究的单分子材料[1]。自旋交叉(Spin Crossover,SCO)现象指的是对于某些第一过渡系金属离子dn(n = 4-7)的配合物,在特定外界条件下(如热、压力、光等)发生低自旋态(Low spin,LS)和高自旋态(High spin,HS)间相互转变的现
Improved Catalytic Activity of a Cd Metal-Organic Framework via Central-metal Exchange in a Single-C
Central-metal exchange offers an attractive strategy for the incorporation of catalytically active metal centers in MOFs.1 For instance,after replacing the inactive CdⅡ ions in porph@MOM-10 with MnⅡ o
Syntheses and crystal structures of two cadmium(Ⅱ)coordination polymers of 1,4-bis((1H-1,2,4-triazol
Triazoles and their derivatives can bridge metal ions in different coordination modes.We synthesized the flexible ligand:1,4-bis((1H-1,2,4-triazol-1-yl)methyl)benzene(bbtz)which possess medium length
As a flexible tripodal ligand with highly flexible arms,tris(2-carboxyethyl)isocyanurate(H3tci)has been widely employed in recent years in coordination chemistry,which holds great flexibility because
Synthesis,crystal structure,luminescence property of uranyl-organic frameworks constructed from trin
A new uranyl-organic coordination complex(UO2)2(C8H5O6N)2(C10H8N2)(H2TPP=Trinitrophenol phthalate)has been synthesized.