【摘 要】
：
近年,金属有机框架材料的研究主要聚焦于性能拓展和多功能复合等方面,如何进行结构设计和修饰剪裁备受关注 [1-2].本文选用具有双官能基团的5 - [2 - 羧基-3-(1H-四唑-5
【机 构】
：
三峡大学理学院,湖北宜昌,443002三峡大学材料与化工学院,湖北宜昌,443002
【出 处】
：
中国化学会2014年中西部地区无机化学化工学术研讨会
论文部分内容阅读
近年,金属有机框架材料的研究主要聚焦于性能拓展和多功能复合等方面,如何进行结构设计和修饰剪裁备受关注 [1-2].本文选用具有双官能基团的5 - [2 - 羧基-3-(1H-四唑-5 -基)-苯氧基]-间苯二甲酸(H3L=5-[2-Carboxy-3-(1H-tetrazol-5-yl)-phenoxy]-isophthalic acid)作为有机构件,通过水热合成法构筑了一例新型铜基MOF([CuHL(H2O)]n)(1).1是一个3-连接2D层状结构且具有hcb拓扑；磁性测试表明,1具有反铁磁性质,光催化实验表明,1有较好的有机染料降解性能,在120分钟内,罗丹明B降解率为96％,甲基橙的降解率为90％.
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