【摘 要】
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Although chemical synthesis has evolved to a relatively advanced state, the ability to prepare well-defined self-assembled materials of controlled shape, si
【机 构】
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School of Chemistry, University of Bristol BS8 1TS, UK
【出 处】
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The 6th International Conference on Nanoscience and Technolo
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Although chemical synthesis has evolved to a relatively advanced state, the ability to prepare well-defined self-assembled materials of controlled shape, size, and structural hierarchy is still in its relative infancy and currently remains the virtually exclusive domain of biology. In this talk the development of a promising new route to such materials, termed living crystallization-driven self-assembly‖ (CDSA), will be described.[1-4] This approach was discovered as a result of an investigation of the solution self-assembly behavior of block copolymers with crystallizable polyferrocenylsilane metalloblocks. It offers an interesting and potentially powerful new route to well-defined micelles and hierarchical materials with controlled dimensions and a variety of potential applications. Moreover CDSA appears to be extendable to a wide range of different crystalline core-forming blocks, including bio- -conjugated materials.
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