The modification of ZnS by doping method is one of the important directions in the research of ZnS nano materials.Doping of transition metal ions in the ZnS matrix has attracted much attention in recent years.Doping transition metal ions can modulate the emission region of ZnS,and improve the efficiency of fluorescence.The doping concentration in the ZnS have determined the distribution,absorption,excitation,emission,and structural properties of particles.