具有笼状结构的Ln12Na6异金属簇合物的合成及磁性研究

来源 :2016年中西部地区无机化学化工学术研讨会 | 被引量 : 0次 | 上传用户:winxb
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  近年来,具有独特构及性质的异金属簇合物成为配位化学的研究热点[1,2]。相比于过渡-稀土异金属簇合物及过渡-过渡异金属簇合物,碱金属-稀土异金属簇合物在核数,形状以及合成方法上都有待于进一步深入探究。
其他文献
  The rational design and construction of metal-organic frameworks have received considerable attention over the past decade because of their interesting vari
会议
  A three-dimensional metal-organic framework (MOF),namely [Cd2(BPDB)2(H2O)]n (1) (2,6-di-p-carboxyphenyl 4,4'-bipyridine1=H2bpydb) has been solvothermal synt
会议
  金属有机框架材料由于其高空隙率、大比表面积以及可调控的空间结构等优点在药物加载与控释的研究中倍受关注.[1,2] 本文合成了配合物{[Cd1.5(tta)(H2O)4.5]·H2O}n (1)(
  Luminescent lanthanide metal-organic frameworks (MOFs) have been attracted extensive attention,not only because of their fantastic structures but also their
会议
  Porous coordination polymers (PCPs),constructed by bridging the metals or clusters and organic linkers,can provide a functional pore environment for gas sto
  Recently,alkaline earth metal complexes have attracted increasing attention of chemists,owing to the aesthetically pleasing structures that many such comple
  近年来,金属-有机框架(MOFs)材料已经广泛应用于气体吸附分离、非均相催化及荧光探针等领域,然而,针对自然界中广泛存在的有毒金属氧酸盐的高效吸附分离研究则相对较少[1]。
  稳定性差和光吸收能力有限从本质上限制了钛多酸(Polyoxotitanate,POT)材料的应用。我们提出一种新的策略通来克服上述不足。通过一步反应同时实现POT 中烷氧基的全羧基
  The rational design and fabrication of attractive and available coordination polymers (CPs) are influenced by many factors such as synthetic methods,reactio
会议
  Metal-organic frameworks (MOFs) have been widely studied because of their intriguing topologies and potential applications as functional materials in differ