Boryl Ligands and Their Roles in Transition Metal Catalysed Borylation Reactions-Insight from Comput

来源 :第十二届全国量子化学会议 | 被引量 : 0次 | 上传用户：kxh8l

【摘要】

：

　　Boryl ligands in transition metal boryl complexes play important roles in many catalytic processes including hydroboration,diboration,and other boron additi

【作者】

：

Zhenyang Lin

【机构】

：

DepartmentofChemistry,TheHongKongUniversityofScienceandTechnology,ClearWaterBay,Kowloon,HongKong

【出处】

：

第十二届全国量子化学会议

【发表日期】

：

2014年6期

下载到本地 , 更方便阅读

下载此文赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

　　Boryl ligands in transition metal boryl complexes play important roles in many catalytic processes including hydroboration,diboration,and other boron addition reactions to unsaturated organics as well as borylation of carbon-halogen and carbon-hydrogen bonds in arenes and alkanes.In this Talk,we discuss selected aspects of metal boryl(M-BR2)chemistry pertaining to the role of boryl ligands in various catalytic processes.The exceptionally strong sigma-donor properties of boryl ligands and their related nucleophilic/electrophilic behaviors will be highlighted.

其他文献

Research on hyperspectral dynamic infrared scene simulation technology

　　The paper presents a hardware in loop dynamic IR scene simulation technology for IR hyperspectral imaging system.Along with fleetly development of new type

会议

Hyperspectral imagingIR scene projectorSpectrum modelingHardware in loop simu

面向太阳能燃料光催化材料

　　光催化可实现光能到化学能的转化，是太阳能转化利用的重要途径，光催化走向应用的关键是发展能在太阳光下高效工作的光催化材料体系。针对控制光催化材料的光吸收、载流子分

会议

光催化水分解

具有磁弛豫的一维稀土体系

　　稀土单离子磁体的控制合成是当前分子磁体的热点研究领域.1 我们通过选择不同的配体，合成了系列具有一维结构的稀土化合物.结构分析表明在这些一维体系中稀土离子具有四方

会议

稀土单离子磁体磁弛豫磁相互作用

改性氧化钙催化双酯交换法制备无甘油生物柴油

　　以氧化钙为催化剂,建立了菜籽油-碳酸二甲酯-甲醇双酯交换法同步制备生物柴油和碳酸甘油酯新体系,所制备的生物柴油各项主要物理化学性能指标均达到欧洲生物柴油标准.催

会议

双酯交换表面改性氧化钙生物柴油

复合能源材料体系电子运动模拟研究

　　围绕能源应用的复合材料体系中的电子态的形成、耦合与转化问题，我们基于第一性原理计算结合量子力学/分子力学基本模拟手段，应用多尺度模拟和密度矩阵框架，与实验紧密结合

会议

复杂分子体系电子态运动非线性光谱

Computational studies on second-order nonlinear optical properties of solid-state materials

　　The solid-state nonlinear optical(NLO)materials play critical roles in the extension of laser frequencies tunnable through unltravoilet to infrared spectros

会议

Ionic association characteristics in mixed chloride saline solution ab initio and classical molecula

Chloride saline solution have been extensively studied for its widely exists in seawater and saline lake,but ionic association characteristics in some mixed sal

会议

Development of Accurate Protein Force Fields

　　Despite several decades intensive efforts,the development of accurate protein force fields remains as a major challenge.1 There are two key issues:(1)How to

会议

What Can We Learn from DFT Calculations in Heterogeneous Catalysis

　　It is well known that there have been great advances made in understanding heterogeneous catalysis from DFT calculations in the last twenty years or so.In t

会议

Molecular Dynamic Simulation Study on the Prenucleation Clusters of Calcium Carbonate in supersatura

　　Calcium carbonates are important biological materials occurring in,for instance,sea urchins,bivalve shells,earthworms,sponges,and avian eggshells,and also a

会议

Boryl Ligands and Their Roles in Transition Metal Catalysed Borylation Reactions-Insight from Comput

与本文相关的学术论文