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采用DFT 揭示了微量水和溶剂DMSO 在苯甲醛与1-烯酰基-1-酰胺基环丙烷阴离子传递反应中的作用机制。与梁课题组提出的氮→氧→碳阴离子传递过程相反，该反应的实际传递过程为氮→碳→氧，该发现进一步被NBO 分析证实。
苯甲醛与1-烯酰基-1-酰胺基环丙烷的阴离子接力反应机理研究
【摘 要】
：
采用DFT 揭示了微量水和溶剂DMSO 在苯甲醛与1-烯酰基-1-酰胺基环丙烷阴离子传递反应中的作用机制。与梁课题组提出的氮→氧→碳阴离子传递过程相反，该反应的实际传递过程
【机 构】
：
东北师范大学化学学院吉林省长春市南关区人民大街 5268 号 130024
【出 处】
：
第十三届全国量子化学会议
【发表日期】
：
2017年期
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