【摘 要】
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In this paper,We synthesized five novel 1D isostructural Zn(Ⅱ)-lanthanide(Ⅲ)heterometallic complexes[LnZn(L)(H2O)(Cl2)]·2DMA·2H2O(Ln=Nd(1),Eu(2),Tb(3),D
【机 构】
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Department of Chemistry,Nankai University,Tianjin,300071
论文部分内容阅读
In this paper,We synthesized five novel 1D isostructural Zn(Ⅱ)-lanthanide(Ⅲ)heterometallic complexes[LnZn(L)(H2O)(Cl2)]·2DMA·2H2O(Ln=Nd(1),Eu(2),Tb(3),Dy(4),Gd(5))and synthesized seven 1D heterometallicframeworks[LnCo(L)(H2O)(Cl2)]·2DMA·H2O(Ln=Pr(6),Sm(7),Eu(8),Dy(9),Tb(10),Gd(11),Tm(12))(H3L=4,4',4〞-(2,2',2〞-nitrilotris(methylene)-tris-(1H-benzo imidazole-2,1-diyl)tris(methylene))-tribenzoic acid; DMA=N,N-dimethylacetamide).
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