【摘 要】
:
镧系金属有机配合物由于其结构的丰富多样,以及他们在吸附、磁性和光学等领域的潜在应用,而受到人们的广泛关注[1-2]。本论文利用水热法合成了两种新的稀土有机配合物:K[E
【机 构】
:
首都师范大学化学系,北京,10048
【出 处】
:
2016年中西部地区无机化学化工学术研讨会
论文部分内容阅读
镧系金属有机配合物由于其结构的丰富多样,以及他们在吸附、磁性和光学等领域的潜在应用,而受到人们的广泛关注[1-2]。本论文利用水热法合成了两种新的稀土有机配合物:K[Eu(2,2-oba)2(phen)2] (1) 和[Eu2(2,2-oba)2(phen)2(ox)(H2O)2] (2) (2,2-oba=2,2二苯醚二甲酸,phen=邻菲罗啉,ox=草酸根离子),通过X-射线单晶衍射确定了它们的的晶体结构。
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