金属钌纳米粒子多相催化剂选择催化加氢肉桂醛

来源 :第十四届全国均相催化学术讨论会 | 被引量 : 0次 | 上传用户:davidrandy
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α 、β-不饱和醇在药物、 农用化学品和 化妆品行业中是很重要的中间原料,而肉桂醛的选择性加氢产物肉桂醇在制药、香料等生产过程中具有重要的作用.
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烯烃的氢甲酰化反应是工业上一个重要的反应,生成的醛可被用于大宗化学品、制药和精细化学品的生产中1.为了增加在工业上更为重要的直链醛的选择性,许多配体都被合成出来,比
有机膦配体以及卡宾类配体拥有非常好的配位能力,在催化领域被广泛应用,尤其是有机膦配体和卡宾配体混合使用的时候,表现出了更好的催化活性.于是在卡宾配体的侧链引入了膦原