As spin carriers,nitronyl nitroxide radicals are appealing building blocks to construct molecular magnetic materials owing to the advantages of their effective exchange interaction and stability.
The studies on molecular materials with optical, electronic and magnetic properties have developed rapidly[1-2].Combining metal and nitronyl nitroxide radical within the same molecular entity is one o
In this work,two series of new lanthanide metal-organic frameworks(Ln-MOFs),{[Ln(L)1.5(H2O)]·DMA·4H2O}n(1-Ln,Ln = Tb,Gd,Dy)and {[La2(L)3]·4H2O}n(2-La),have been successfully assembled by Ln3+ions and
By treating a semirigid 5-oxyacetate isophthalic acid(H3OAIP)ligand with MnSO4/CoSO4/CdSO4 under solvothermal conditions,three isostructural cluster organic frameworks,[M2(OH)(OAIP)(DMA)]·H2O(M=Mn2+(1
A new three-dimensional(3D)luminescent metal-organic framework(MOF)[Zn2(L)2]·2DMA·3H2O(1)[H2L = 2-(imidazol-1-yl)terephthalic acid] have been solvothermally synthesized by d10 Zn(Ⅱ)ions and H2L in dif
A series of alkaline earth-metal organic frameworks(AE-MOFs),i.e.{[Mg2(μ6-L)(μ2-OH2)(H2O)4]·DMF}n(1),[Ca2(μ10-L)(EtO)]n(2),[Sr(μ6-H2L)(MeO)]n(3)and {[Ba1.5(μ5-H2L)(μ4-H3L)(H2O)3]·2(H2O)}n(4)were synth