邻菲啰啉-膦配体的Co,Ni配合物的光增强HER性能探索

来源 :中国化学会第十届全国无机化学学术会议 | 被引量 : 0次 | 上传用户:liyan76669956
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  设计合适的光电化学(PEC)催化剂是将光和电能转化为化学能的关键问题之一。我们将含有光活性的邻菲啰啉基团和具有强配位能力的二苯基膦结合获得了2-二苯基膦基甲基氨基邻菲啰啉这一新型含膦配体。
其他文献
The lanthanide-based complexes have attracted much attention in the field of molecular magnetism for they are excellent candidates of SMMs [1-2].
金属-有机框架材料(MOFs)中发色团配体的局部浓度及空间排列方式对其光电性能有着重要影响。芘和卟啉均是高度共轭的分子构筑单元,常被用来构筑新型光电材料。
As spin carriers,nitronyl nitroxide radicals are appealing building blocks to construct molecular magnetic materials owing to the advantages of their effective exchange interaction and stability.
The studies on molecular materials with optical, electronic and magnetic properties have developed rapidly[1-2].Combining metal and nitronyl nitroxide radical within the same molecular entity is one o
In this work,two series of new lanthanide metal-organic frameworks(Ln-MOFs),{[Ln(L)1.5(H2O)]·DMA·4H2O}n(1-Ln,Ln = Tb,Gd,Dy)and {[La2(L)3]·4H2O}n(2-La),have been successfully assembled by Ln3+ions and
By treating a semirigid 5-oxyacetate isophthalic acid(H3OAIP)ligand with MnSO4/CoSO4/CdSO4 under solvothermal conditions,three isostructural cluster organic frameworks,[M2(OH)(OAIP)(DMA)]·H2O(M=Mn2+(1
A new three-dimensional(3D)luminescent metal-organic framework(MOF)[Zn2(L)2]·2DMA·3H2O(1)[H2L = 2-(imidazol-1-yl)terephthalic acid] have been solvothermally synthesized by d10 Zn(Ⅱ)ions and H2L in dif
A series of alkaline earth-metal organic frameworks(AE-MOFs),i.e.{[Mg2(μ6-L)(μ2-OH2)(H2O)4]·DMF}n(1),[Ca2(μ10-L)(EtO)]n(2),[Sr(μ6-H2L)(MeO)]n(3)and {[Ba1.5(μ5-H2L)(μ4-H3L)(H2O)3]·2(H2O)}n(4)were synth
光功能配合物因其良好的氧化还原活性和组装能力,分子结构易修饰,及丰富的轨道吸收和强旋轨耦合等特点,在分子电子学、近红外电致变色、信息存储及电致发光器件等诸多方面应用广泛。
本文选用3-甲酰基苯氧乙酸缩氨基硫脲(L)为配体,通过溶剂热法合成了一个Zn 配合物{[Zn3(L)2]。(CH2OH)2}n,并进行了x 射线单晶结构表征。