Copolymerization of Ethylene with Vinyl Trifluoromethyl Dimethylsilane Promoted by Novel Bridged Non

来源 :2013 International Symposium on Integrated Molecular / Mater | 被引量 : 0次 | 上传用户:wnt
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  It is grand challenges for the metal-catalyzed olefin polymerization to copolymerize nonpolar olefins with polar functional olefins [1].In this work a series of novel ansa-nonmetallocene catalysts with salicylaldehyde ligands was synthesized by the treatment of dimethyldichlorosilane, substituted salicylaldehyde with TiCl4, ZrCl4, NiCl2 and PdCl2 in THF.
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