Shaped Nanoobjects from Bulk Microphase-Separation of Block Copolymers without Chemical Crosslinking

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  Bulk self-assembly of block copolymers(BCPs)produces various ordered nanostructures.By this property,dispersible core/shell polymeric nanoobjects(PNOs)have been prepared by first BCP bulk microphase separation,then chemically crosslinking the uncontinuous domains,and finally dispersing in a solvent.[1] Since the particle morphologies are inherited from the bulk microphase separated structures,it is easily to fabricate the core/shell PNOs with lamellar,cylindrical and spherical morphologies from the same block copolymer family by changing the composition.
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