The chromatographic separation of chiral compounds is an important tool in the search for new pharmaceutical entities.Both HPLC and SFC separations of chiral chemicals are important tools for analytical determination and preparative isolation of enantiomeric mixtures.Existing chiral stationary phases can separate a wide variety of chiral mixtures.However there are still enantiomeric mixtures that are difficult to separate limiting their characterization.It is the focus of this study to characterize and understand the separation capabilities for new halogen containing carbohydrate based chiral stationary phases that we have developed.In addition to reporting the separation capabilities of the new phases we will also report on the loading capacity and overall robustness for these new phases.