Adsorption Breakthrough Curves for Alkaline-earth Metal Ions on the Resins in A Fixed-bed Column

来源 :第七届国际分离科学与技术会议(Proceedings of the 7th International Conferen | 被引量 : 0次 | 上传用户:GYQ865739853
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  A column sorption study was carried out by using four resins (D113,D001,LS-1000,LS-5000) for the adsorption of alkaline-earth metal ions from aqueous solutions.The breakthrough curve was obtained as a function of feed flow rate,and the total and breakthrough capacity values of the resins were calculated.Four kinetic models: Adams-Bohart,Wolborska,Thomas and Yoon-Nelson models were applied to experimental data to predict the breakthrough curves of Na-form resins and to determine the characteristic parameters of the column useful for process design.All models were found suitable for describing the whole or a definite part of the dynamic behavior of the column with respect to flow rate and inlet ion concentration.Otherwise,the breakthrough curves for Mg2+,Ca2+,Sr2+ on the four Na-form resins in the mixed solution of alkaline-earth metals were also obtained.The results obtained would be helpful for the understanding of the competitive adsorption processes and the recovery or removal of one or more alkaline-earth metal ions from aqueous solutions.
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