SURFACE MODIFICATION VIA AQUEOUS COPPER MEDIATED LIVING RADICAL POLYMERIZATION “GRAFTING TO” AND “GR

来源 :The 6th International Symposium on Polymer Chemistry(2014年第六 | 被引量 : 0次 | 上传用户：niehaibin

【摘要】

：

Aqueous copper mediated living radical polymerization has been developed as a powerful tool to synthesize a series of functional water-soluble polymers with con

【作者】

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Qiang Zhang Alex Simula Gabit Nurumbetov Yunhua Chen David M.Haddleton

【机构】

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DepartmentofChemistry,UniversityofWarwick,CoventryCV47AL,UnitedKingdom

【出处】

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The 6th International Symposium on Polymer Chemistry(2014年第六

【发表日期】

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2014年6期

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Aqueous copper mediated living radical polymerization has been developed as a powerful tool to synthesize a series of functional water-soluble polymers with controlled chain length and narrow molecular weight distribution.1 This strategy utilized a tetradentate tertiary amine-based ligand,Tris[2-(dimethylamino)ethyl]amine (Me6TREN),which has been concluded as not suitable for aqueous atom transfer radical polymerization (ATRP) due to very fast disproportionation of CuIX/Me6TREN in water.

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SURFACE MODIFICATION VIA AQUEOUS COPPER MEDIATED LIVING RADICAL POLYMERIZATION “GRAFTING TO” AND “GR

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